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17春吉大网院《无机化学(含实验)》毕业清考课程考试

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发表于 2017-5-6 10:29:53 | 显示全部楼层 |阅读模式
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无机化学(含实...
一、单选 ( 每题2分, 共25道小题, 总分值50分 )
1.(2分)

0.117 mol·dm-3 蔗糖溶液在37℃时的渗透压为( )

    A. 301.5 Pa
    B.

    291.8 Pa
    C.

    301.5 KPa
    D.

    291.8 KPa

是否存疑
2.(2分)

下列各套量子数(n,l,m,ms)中,不可能存在的是:(_____)

    A. 3,1,2,+image8.png
    B. 3,2,1,-image8.png
    C. 2,1,1,-image8.png
    D. 2,1,0,-image8.png

是否存疑
3.(2分)

下列分子中相邻共价键的夹角最小的是:(_____)

    A. H2O
    B.

    NH3
    C.

    CCl4
    D.

    BF3

是否存疑
4.(2分)

不是共轭酸碱对的一组物质是:( )

    A.

    NH3-NH2-
    B.

    [Al(OH)2(H2O)4]+ -[Al(OH)3(H2O)3]
    C.

    H3O+ -OH-
    D.

    HS--S2-

是否存疑
5.(2分)

在HAc水溶液中加入NaAc使HAc解离度降低,在CaCO3饱和溶液中加入Na2CO3,

    A. 前者叫同离子效应,后者叫盐析
    B. 两者均属同离子效应
    C. 前者叫同离子效应,后者叫盐效应
    D. 两者均属盐效应

是否存疑
6.(2分)

下列分子中电偶极矩为零的是__________

    A. CO2
    B. CH3Cl
    C.

    NH3
    D.

    HCl

是否存疑
7.(2分)

下列各系统中,分子间存在的作用力同时具有氢键、色散力、诱导力和取向力的是( )

    A.

    液态CO2
    B.

    氨水
    C. I2的CCl4溶液
    D. 液态Br2

是否存疑
8.(2分)

基态氮原子的价层电子组态为:( )

    A. blob.png
    B. blob.png
    C. 2s22p2x2py1
    D. 2s22p3

是否存疑
9.(2分)

已知298K时,Ksp (Ag2CrO4)=1.0×10-12 。则在该温度下,Ag2CrO4在0.010 mol·L-1 AgNO3

溶液中的溶解度是_____

    A.

    1.0×10-10 mol·L-1
    B.

    1.0×10-8 mol·L-1
    C.

    1.0×10-5 mol·L-1
    D.

    1.0×10-6 mol·L-1

是否存疑
10.(2分)

在分子中衡量原子吸引成键电子的能力用( )

    A.

    电离能
    B.

    电子亲和能
    C.

    电负性
    D.

    解离能

是否存疑
11.(2分)

0.10 mol·dm-3下列物质中,在相同温度下渗透压最大的是( )

    A.

    糖水
    B. C2H5OH溶液
    C.

    NaCl溶液
    D. MgCl2溶液

是否存疑
12.(2分)

在相同温度下,和1%尿素[CO(NH2)2]水溶液具有相同渗透压的葡萄糖(C6H12O6)溶液的浓度约为( )

    A.

    2%
    B.

    4%
    C.

    5%
    D.

    3%

是否存疑
13.(2分)

下列分子中,中心原子的杂化轨道采取sp2杂化的是: ( )

    A.  CHCl3   
    B.  NH3
    C. CH4   
    D. BCl3

是否存疑
14.(2分)

第四周期元素基态原子中,未成对电子数最多可达_____

    A. 4
    B. 5
    C. 6
    D. 7

是否存疑
15.(2分)

已知反应2NH3=N2+3H2,在恒温下平衡常数为a,则N2+3H2 =2 NH3,

反应的平衡常数为:( )

    A.

    2a
    B.

    a
    C.

    1/a
    D. a2

是否存疑
16.(2分)

0.4 mol·L-1HAc 溶液中的H+ 浓度是0.1mol·L-1HAc 溶液中 H+ 浓度的 ( )

    A.

    1倍
    B.

    2倍
    C.

    3倍
    D.

    4倍

是否存疑
17.(2分)

是V字形分子,原子成键的可能杂化轨道类型是( )

    A.

    2个P轨道
    B.

    SP杂化
    C. SP3不等性杂化
    D. SP2杂化

是否存疑
18.(2分)

Pauling 的电负性值可以预言 ( )

    A.

    配位数
    B.

    偶极矩
    C.

    分子的极性
    D.

    键的极性

是否存疑
19.(2分)

基态19K原子最外层电子的四个量子数可能是( )

    A.

    4,0,0,[)29}}GE7K9}A()BRV]A_IN.png
    B.

    3,1,0,[)29}}GE7K9}A()BRV]A_IN.png
    C.

    3,1,0,$W(PTHVSMXZGC]2AGGJQY2B.png
    D.

    3,1,-1,$W(PTHVSMXZGC]2AGGJQY2B.png

是否存疑
20.(2分)

根据医学临床上的规定,下列溶液中属于等渗溶液的是_____

    A.

    0.10mol·L-1 NaCl溶液
    B.

    0.30mol·L-1  NaCl溶液
    C.

    0.15mol·L-1 葡萄糖溶液
    D.

    0.30mol·L-1  葡萄糖溶液

是否存疑
21.(2分)

HAc的KaӨ=1.76×10-5,若用HAc和NaAc溶液混合配制pH = 4.5的缓冲溶液,则二者浓度之比为 ( )

    A. 1/1.8
    B. 3.2/36
    C. 1.8/1
    D. 8/9

是否存疑
22.(2分)

下列电子构型中,属于激发态的是:( )

    A. 1s22s22p63s1
    B. 1s22s22p63s23p63d54s1
    C.

    1 s22s22p1
    D.

    1s22s12p1

是否存疑
23.(2分)

在H2和He分子间存在的分子间作用力是 ( )

    A.

    诱导力
    B.

    色散力
    C.

    氢键
    D.

    取向力

是否存疑
24.(2分)

n=4、l=2 的原子轨道能级上,电子处于半充满时,应有的电子数为(_____)

    A.

    7
    B.

    10
    C.

    3
    D.

    5

是否存疑
25.(2分)

下列分子中采用sp3不等性杂化成键分子的空间构型为三角锥型的是: (_____ )

    A.

    BCl3
    B.

    H2O
    C.

    CH4
    D.

    NH3

是否存疑
二、判断题 ( 每题2分, 共25道小题, 总分值50分 )
1.(2分)

每周期的元素数目等于相应于它所在的能级组的轨道数。

是否存疑
2.(2分)

基态Cu原子的价层电子构型是3d104s1。

是否存疑
3.(2分)

在一定温度下,某两种酸的浓度相等,其水溶液的pH值也相等。

是否存疑
4.(2分)

同浓度的NH4Cl溶液与NaOH溶液等体积混合,达平衡时,其平衡常数等于氨水的解离平衡常数的倒数。

是否存疑
5.(2分)

由HA.c-NaA.c组成的缓冲溶液,若溶液中B.(HA.c)>B.(NaA.c),则该缓冲溶液抵抗外来酸的能力大于抵抗外来碱的能力。

是否存疑
6.(2分)

两种同型的难溶强电解质相比较,标准溶度积较大的其相应的溶解度(以mol·L-1为单位)也一定大。

是否存疑
7.(2分)
弱酸或弱碱的浓度越小,其解离度也越小,酸性或碱性越弱。

是否存疑
8.(2分)
将氢原子的一个电子从基态激发到4s或4F轨道所需要的能量相同。

是否存疑
9.(2分)

常利用稀溶液的渗透压法来测定大分子溶质的相对分子质量。( )

是否存疑
10.(2分)

在一定温度下,由于纯水、稀酸和稀碱中的b(H+)不同,所以水的离子Kw⊖也不同。

是否存疑
11.(2分)

因KsӨ(A.gCl)=1.56F10-10 > KsӨ(A.g2CrO4)=9F10-12 所以A.gCl的溶解度比A.g2CrO4的大。

是否存疑
12.(2分)

氢原子的3p能级与3d能级相等。

是否存疑
13.(2分)
同离子效应能使弱电解质的解离度减小,也能使难溶电解质的溶解度降低。

是否存疑
14.(2分)

两种难溶强电解质相比较,标准溶度积较大的其相应的溶解度(以mol·L-1为单位)也一定大。

是否存疑
15.(2分)
用EDTA.做重金属的解毒剂是因为其可以降低金属离子的浓度。

是否存疑
16.(2分)

当二元弱酸的K2Ө<<K1Ө时,酸根离子的浓度在数值上近似等于K2Ө,与酸的起始浓度关系不大。

是否存疑
17.(2分)
相同温湿度下,欲使被理想半透膜隔开的两种稀溶液间不发生渗透,应使两溶液的渗透浓度相等。

是否存疑
18.(2分)
缓冲溶液用水适当稀释时,溶液的pH值基本不变,但缓冲能力减小。

是否存疑
19.(2分)

HgCl2 与HCN 都是直线型分子,故它们都是非极性分子。

是否存疑
20.(2分)
一般双原子分子中键的极性越大,则分子的极性越大。

是否存疑
21.(2分)

用公式c(H3O)+= image1.png 计算一元弱酸HA.溶液中H3O+浓度是有条件的。一般说来,当c0/Kay >500时,才能应用此公式。

是否存疑
22.(2分)
键具有极性,组成的分子必定是极性分子。

是否存疑
23.(2分)

角量子数l主要决定核外电子的能量。

是否存疑
24.(2分)
核外电子的能量只与主量子数有关。

是否存疑
25.(2分)

PH3是正三角形结构,其为非极性分子。

是否存疑
倒计时 89:59

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谋学网友  发表于 2018-3-31 14:12:23
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